In 2010, she was a member of the senior women's national team that competed at the World Championships in the Czech Republic. She was important to the team's success. In July 2010, she participated in a four-day training camp and one game test match against the United States in Connecticut, but missed the Olympic qualification series in July 2011 because of WNBA commitments. Nonetheless, she was named to the 2012 Australia women's national basketball team. In February 2012, she was named to a short list of 24 eligible players to represent Australia at the 2012 London Olympics. In late April and early May 2012, she was one of four Australian "big" players to participate in a special training camp for the team, and participated in the national team training camp held from 14 to 18 May 2012 at the Australian Institute of Sport. Cambage was seen as a key component if Australia is to beat the United States in London. At the 2012 Olympic Games on 2 August, Cambage successfully dunked the basketball with one hand in a 70–66 victory over Russia. Although it was generally believed[by whom?] to be the first successful dunk by a female athlete to take place during the Olympic Games, FIBA have yet to confirm if this is the case.  Cambage and the Opals won a bronze medal in London with an 83–74 win over Russia.