Basically what you're looking for is a good, solid foundation of existing paint that is stable and still strongly bonded to the car. Many times an original factory paint job, even after decades will meet these criteria.
When choosing colours for exterior surfaces, consider the style of the brickwork or masonry of your home along with the colours used on nearby buildings, so as to pick colours that are sympathetic to these surroundings. Colours for fences and sheds should be selected with the same criteria in mind.
Solvent or oil-based paints are used where a tough, durable finish is required for interior and exterior timber, masonry and furniture - although, as mentioned above, the new generation of acrylics and multi-surface paints offers viable alternatives. In general, brushes need to be cleaned with turpentine or white spirit.
Alkyd is an old interior paint made newly popular by a change in solvent - a super-refined petroleum chemical that has almost no odor. It is not a water paint. You thin it and clean brushes with mineral spirits or turpentine, or, if you want to retain the odorless feature, with the new odorless solvent. (Ask the paint-store man for just that, odorless solvent).
When you plan with split complementary colors, you begin with a single reference color. Next, choose a color from either edge of the complementary color and use it. While the complementary color scheme is a little more obvious, this scheme can fail totally if you just use paler versions of your warm colors. By the same token, picking a a warm undertone for the main contrasting color and combining it with two cool tones will showcase the warm tone.
Traditionally, the solvents or VOCs and other chemicals used to make paints easier to apply give off toxic fumes that seep into the atmosphere for years after application. Paints with reduced or no VOCs are healthier for decorators and the people whose homes are painted with them.
Another idea keeping Paint Brush moist until the next paint coat is applied (but not leaving for extended periods) is leaving Brush in container, wrapping top with plastic, sticking handle out the top, and taping around the can. This resembles the Maxwell House Coffee Container mentioned earlier. If plastic and masking tape is still not available, and time between coats is not very long, take that sopping wet rag, draping over the top of paint bucket with Paint Brush still in it. This technique works best when using Latex waterborne paints.